Stokhiometri
Stoichiometry /ˌstɔɪkiˈɒmᵻtri/ is the calculation of relative quantities of reactants and products in chemical reactions.
Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of product can be empirically determined, then the amount of the other reactants can also be calculated.
This is illustrated in the image here, where the balanced equation is:
CH4 + 2 O2 → CO2 + 2 H2O.
Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water. Stoichiometry measures these quantitative relationships, and is used to determine the amount of products/reactants that are produced/needed in a given reaction. Describing the quantitative relationships among substances as they participate in chemical reactions is known as reaction stoichiometry. In the example above, reaction stoichiometry measures the relationship between the methane and oxygen as they react to form carbon dioxide and water.
Because of the well known relationship of moles to atomic weights, the ratios that are arrived at by stoichiometry can be used to determine quantities by weight in a reaction described by a balanced equation. This is called composition stoichiometry.
Gas stoichiometry deals with reactions involving gases, where the gases are at a known temperature, pressure, and volume and can be assumed to be ideal gases. For gases, the volume ratio is ideally the same by the ideal gas law, but the mass ratio of a single reaction has to be calculated from the molecular masses of the reactants and products. In practice, due to the existence of isotopes, molar masses are used instead when calculating the mass ratio.
Stoichiometry is not only used to balance chemical equations but also used in conversions, i.e., converting from grams to moles using molar mass as the conversion factor, or from grams to milliliters using density. For example, to find the amount of NaCl (sodium chloride) in 2.00 g, one would do the following:
In the above example, when written out in fraction form, the units of grams form a multiplicative identity, which is equivalent to one (g/g = 1), with the resulting amount in moles (the unit that was needed), as shown in the following equation,
Stoichiometry is often used to balance chemical equations (reaction stoichiometry). For example, the two diatomic gases, hydrogen and oxygen, can combine to form a liquid, water, in an exothermic reaction, as described by the following equation:
2 H2 + O2 → 2 H2O
Reaction stoichiometry describes the 2:1:2 ratio of hydrogen, oxygen, and water molecules in the above equation.
The molar ratio allows for conversion between moles of one substance and moles of another. For example, in the reaction
2 CH3OH + 3 O2 → 2 CO2 + 4 H2O
the amount of water that will be produced by the combustion of 0.27 moles of CH
3OH is obtained using the molar ratio between CH
3OH and H
2O of 2 to 4.
The term stoichiometry is also often used for the molar proportions of elements in stoichiometric compounds (composition stoichiometry). For example, the stoichiometry of hydrogen and oxygen in H2O is 2:1. In stoichiometric compounds, the molar proportions are whole numbers.
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